Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensing.
نویسندگان
چکیده
Polyurethane nanocomposites with high content of red NIR luminescent transition metal clusters are presented. The gas permeability of the hybrid material is controlled by adjusting the hard/soft segment ratio of the organic matrix structure leading to a drastic and reversible enhancement of cluster luminescence depending on the molecular oxygen concentration in its surrounding atmosphere.
منابع مشابه
Phosphorescent Platinum(II) and Palladium(II) Complexes with Azatetrabenzoporphyrins—New Red Laser Diode-Compatible Indicators for Optical Oxygen Sensing
A new class of oxygen indicators is described. Platinum(II) and palladium(II) complexes of azatetrabenzoporphyrins occupy an intermediate position between tetrabenzoporphyrins and phthalocyanines and combine features of both. The new dyes are excitable in the red part of the spectrum and possess strong room-temperature NIR phosphorescence. Other features include excellent spectral compatibility...
متن کاملAbstract 42: Human Adipose-Derived Stem Cells with BRCA Mutation Promote Breast Tumor Cell Migration
F ray, M ay 5, 2017 RESULTS: Laser Doppler flowmetry confirmed a reactive hyperemia following tourniquet release. In addition, both the phosphorescence lifetime biosensor and NIR methods suggested that the tissue O 2 content temporarily but significantly exceeded baseline following tourniquet release (p<0.05). We term this phenomenon reactive hyperoxia. This suggests that the O 2 supply transie...
متن کاملInvestigation of the synergistic effect of titania micro and nanoparticles on the hydrophobic properties of polyurethane composite coating
One of the ways to improve the performance of ceramic insulators in polluted climates is to use polymer coatings reinforced with ceramic particles. The purpose of this study is to compare the effect of adding Titania nanoparticles and Titania micro-nanoparticles on hydrophobic properties of PU. In this method, stearic acid, which is a cheap and environmentally friendly material, was used for su...
متن کاملDesign and Integration in Electro-Optic Devices of Highly Efficient and Robust Red-NIR Phosphorescent Nematic Hybrid Liquid Crystals Containing [Mo6I8(OCOCnF2n+1)6]2– (n = 1, 2, 3) Nanoclusters
متن کامل
Hybrid Nanomaterials Based on Graphene and Gold Nanoclusters for Efficient Electrocatalytic Reduction of Oxygen
Nanocomposites based on gold nanoclusters (AuNCs) with polyvinyl pyrrolidone as ligand and reduced graphene oxide (RGO) have been prepared and employed as efficient electrocatalysts for oxygen reduction reaction (ORR). AuNCs were synthesized through a wet chemical approach and then loaded onto the RGO. The as-prepared hybrid materials were pyrolyzed to remove the organic ligands. The composites...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 51 38 شماره
صفحات -
تاریخ انتشار 2015