Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensing.

نویسندگان

  • Maria Amela-Cortes
  • Serge Paofai
  • Stéphane Cordier
  • Hervé Folliot
  • Yann Molard
چکیده

Polyurethane nanocomposites with high content of red NIR luminescent transition metal clusters are presented. The gas permeability of the hybrid material is controlled by adjusting the hard/soft segment ratio of the organic matrix structure leading to a drastic and reversible enhancement of cluster luminescence depending on the molecular oxygen concentration in its surrounding atmosphere.

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عنوان ژورنال:
  • Chemical communications

دوره 51 38  شماره 

صفحات  -

تاریخ انتشار 2015